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1) Give the name of the functional group indicated in the molecules below for Fl You do not have to do AE or J CH3 N HN H₂Ñ OCH3 ОН N H3C а inkage) I sildenafil (Viagram) h aspartame (artificial sweetner) 2) Please draw structures for compounds named below A) 1chloro3ethylhexane B) 5tertbutyl1,2dichloro2,3dimethyloctane 3 Common name 1) Name the alkyl group in alphabetical order and then add the word amineIn case the two alkyl groups are same, the numerical prefix di is used before the name of the alkyl group 2) Add the prefix Nalkyl before the name of the aminoalkane ;N,NDimethylformamide HCON (CH3)2 PubChem

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N(ch3)2 functional group name

N(ch3)2 functional group name-Secondary (2°), or tertiary (3°) CH3CH2CH2 N H H CH3 N CH3 CH3 CH3CH2CHCH3 NH2 CH3CH2 N H CH3 N H N 6 Nomenclature of Amines • Simple 1°, 2°, and 3° amines common (trivial) names are obtained by alphabetically arranging the names of the alkyl substituents on the nitrogen and adding the suffix amine (eg, ethylmethylamine) Find an answer to your question Name a functional group present in (i) CH3CHO, (ii) C2H5COOH Bubbiya8monika Bubbiya8monika CBSE BOARD X Secondary School answered Name a functional group present in (i) CH3CHO, (ii) C2H5COOH 2

I 10 Identify The Functional Group Of The Following Compound Ch3 C H

• contain an "amino" group – a N atom bonded to 1, 2, or 3 carbon atom groups by single bonds H Aldehydes and Ketones • contain a C=O ("carbonyl") group • note that in condensed structural formulas, the aldehyde group may be written as –CH=O or as –CHO I Carboxylic AcidsCH 3 CH 3—CH 2—NH 2 CH 3—NH—CH 3 ethylamine dimethylamine CH 3—N—CH 2—CH 3 ethyldimethylamine Name the following amines IUPAC Names of Amines • Amines are named as alkanamines • The –e in the alkane name of the longest chain is changed to –amine NH 2 • The chain is numbered to locate the amine group and substituents CH 3—CH 2—NH 2 CHFUNCTIONAL GROUPS and Their Names Compound type Functional group Simple Example Name ending Alkene (double bond) CH 3CHCH 2 Propeneene Alkyne (triple bond) CH 3CCH Propyneyne Arene (aromatic) Benzene None Halide X = F Cl, Br, I CH 3CH 2I Iodoethane or Ethyl Iodide None Alcohol CH 3CH 2OH Ethanolol Ether CH 3CH 2O CH 2CH 3 Ethoxyethane or

Organic molecules are also named using the functional group approach 2hexanone 2hexanol 2chlorohexane The rule is that functions assume their distinct identity when separated by –CH2– groups Thus, the carbonyl, C=O, and hydroxy, OH, of a carboxylic acid, RCOOH, are part of a single function and are NOT "alcoholplusketone"Chapter 3 Alcohols, Phenols, and Ethers 2 3 Alcohols 4 The Hydroxy (—OH) Functional Group •The hydroxyl group (—OH) is found in the alcohol and phenol functional groups (Note that's not the same as hydroxide, OH, which is ionic) –in alcohols, a hydroxyl group is connected to a carbon atom –in phenols, —OH is connected to a benzene ringC Functional Groups Compound Classification Compound Classification CH 3 —OH alcohol CH 3 —NH 2 amine O CH 3 —C—NH 2 amide carboxylic acid H 2 C CH 2 aldehyde CH 3 —O—CH 3 ether ketone carboxylic acid Q7 Classify each of the following according to its functional group a alkene CH 3 —CH 2 —CH=CH—CH 3

 Study Notes The concept of functional groups is a very important one We expect that you will need to refer back to tables at the end of Section 31 quite frequently at first, as it is not really feasible to learn the names and structures of all the functional groupsAmides (RCONH 2) take the suffix "amide", or "carboxamide" if the carbon in the amide group cannot be included in the main chainThe prefix form is both "carbamoyl" and "amido" Amides that have additional substituents on the nitrogen are treated similarly to the case of amines they are ordered alphabetically with the location prefix N HCON(CH 3) 2 is N,NCH 3 CH 2 NHCH 2 CH 3;

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General Information Alkane Names & Functional Groups Alkane Names Primary, Secondary, Tertiary & Quaternary Carbons Common Functional Groups Download pdf Alkane Names Number of carbons (n) Name Formula ( C n H 2n2) 1 methane CH 4 2 ethane C 2 H 6 3 propane C 3 H 8 4 butane C 4 H 10 5 pentane C 5 H 12 6 hexane C 6 H 14Alcohol CH3CH2CH2OH ether CH3CH2OCH3 aldehyde CH3CH2CH2CHO ketone CH3COCH3 carboxylic acid CH3CH2CH2CH2COOH ester CH3CH2COOCH3 amine (2*) CH3CH2NHCH3 The common formula of ether is Cn H2nO, which satisfy the general formula of alcohol So the functional isomer of ether is obviously alcohol compound with functional group –OH Now, CH 3 CH 2 – O – CH 3 compound contain three carbon atoms Hence the molecular formula of the isomeric alcohol would be C3H8O and the name of the alcohol is

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(a) CH 3 CH 2 CH 2 OH (b) CH 3 CH(OH)CH 3 (c) CH 3 CH 2 CH 2 CHO (Note This is one way to write an aldehyde) (d) CH 3 CH 2 CH 2 CH 3 (e) none of the above 6 Which of the following compounds is a functional group isomer of C 2 H 5 OH, ethanol (ethyl alcohol)?The blue atom is the nitrogen atom Notice in methylamine the carbon atom of the methyl group is bonded to the nitrogen In amines the nitrogen atom alway has three bonding groups and one lonepair amine (CH 3) 2 NH dimethylamine In this example of an amine two R groups are bonded to the nitrogen amine (CH 3) 3 N trimethylamineTable 12 Common Functional Grou Name Functional Group Example Acyl halido Alcohol Aldehydo Alkano Alkono Alkyl halide Alkyno Amido AmineEx;cELH #H;cc)c=c(;cxC=CEN(;cN(Aromatic ring @ Carboxylic acid jgow Diene )C=CC=C(E star j8pe Ethor CPLC Kotono Cgc Nitrjl® CC=N Organomotallic CM cH38§E H3CELH H3Cj8H H3CCH3 H2C=CH2 H3C

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Functional Groups A functional group is a defined grouping of atoms in an organic molecule A given functional group exhibits a characteristic set of chemical properties, which are largely independent of the rest of the structure of the molecule in which it is foundOrganic Functional Group List Functional Group Compound Prefix/Suffix Example IUPAC Name (Common Name) RH alkane ane CH 3CH 3 ethane CC alkene ene H 2C=CH 2 ethene (ethylene) CC alkyne yne HC≡CH ethyne (acetylene) RX haloalkane halo CH 3Cl chloromethane ROH alcohol ol (hydroxy) CH 3OH methanol RNH 2 amine amine (amino) CH 3CH 2NHEthyl ether CH 3CH 2OCH 2CH 3 not so polar (symmetric) some lipids esterCOOR methyl ester of acetic acid CH 3COOCH 3 polar not charged fats (eg, triglycerides) detail O COR amideCONH 2 acetamide CH 3CONH 2 polar, not charged proteins (eg, asparagine) detail O CNH 2 sulfhydrylSH 2mercaptoethanol HOCH 2CH 2SH

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Elimination Alkenyl halides CH 2 =CHCl Chloroethene or vinyl chloride Electrophilic addition;4 Thiols and Amines H3CC OH CH3 H OH H3CC SH CH3 H SH H3CC NH2 CH 3 H N CH3 CH alcohols thiols amines Ethers The etherfunctional group is described as an sp3oxygen atom bonded to two carbon atoms, and may be symbolized as ROR' R and R' may be the same groups or different CH 3CH 2O CH CH CH3 O C CH3 CH3 CH3 O CarbonylContaining Functional A methyl group is an alkyl derived from methane, containing one carbon atom bonded to three hydrogen atoms — CH3 In formulas, the group is often abbreviated Me Such hydrocarbon groups occur in many organic compounds It is a very stable group in most molecules While the methyl group is usually part of a larger molecule, it can be found on its own in any of

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Propyl The reaction for the combustion of heptane isWhich one of the following compounds is an isomer of CH 3 CH 2 CH 2 CH 2 OH?The functional group here is amine and it's 2nd suffix is amine only so amine is written after the main chain name and main chain name is Meth as it contain 1 carbon Here 1st suffix is anewe have removed the' e ' from ane because the 2nd suffix ( amine) starts with a vowel and it contains 2 methyl group that's why it's written dimethyl in the prefix

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CH3O CH3CHCH2COH pentanoic acid 2methylbutanoic acid O 3methylbutanoic acid O 2methyl butyric acid O 2methyl4butanoic acid Esters are formed from the reaction of an ether with a carboxylic acid CH3NCH2CH3 CH3 True False The common name of CH3CH2OCH2CH3 is dimethyl ether diethyl ether(1) the hybridization about carbon is sp² Give the IUPAC name of (a) (CH 3) 2CHCH 2CH 2CH 3 (b) (C 2H 5) 2C(CH 3)CH 2CH 3 (c) 3 CH 3CH 2CHCH 2CHCH 2CH 3 CH CH 2CH CH 3Esterification Phenols C 6 H 5 OH Phenol

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Functional Group Molecular Formula IUPAC name general name/ Structure Characteristics Alkanes CH4 methane all single bonds (sigma) C2H6 CH3CH3 ethane sp3 hybridized HCON(CH3)2 N,Ndimethylmethanamide generally soluble in water CH3CONH2 ethanamide acetamide O OH O OCH 2 CH 3 O O O NH 2 NH 2 OOrganic Chem Function Groups And Names by lokisare9 , Sep 07 Subjects chem functional groups organic Click to Rate "Hated It" Click to Rate "Didn't Like It" Click to Rate "Liked It" Click to Rate "Really Liked It" Click to Rate "Loved It" 45 1Problem Set 2 Hydrocarbons and Functional groups ANSWER KEY Chemistry 260 Organic Chemistry 1 Which of the following statements about ethane is true?

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What is the IUPAC name of CH3CH2CH2CH2N(CH3)2?Functional Group Name Example Alkane CH 3 CH 2 CH 3 (propane) Alkene CH 3 CH=CH 2 (propene) Alkyne CH 3 C CH (propyne) F, Cl, Br, or I Alkyl halide CH 3 Br (methyl bromide) Alcohol CH 3 CH 2 OH (ethanol) Ether CH 3 OCH 3 (dimethyl ether) Amine CH 3 NH 2Trimethylamine is a tertiary amine that is ammonia in which each hydrogen atom is substituted by an methyl group It has a role as a human xenobiotic metabolite and an Escherichia coli metabolite It is a tertiary amine and a member of methylamines It is a conjugate base of a trimethylammonium

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 The eponymous member of this grouping is the carboxylic acid functional group, in which the carbonyl is bonded to a hydroxyl (OH) group As the name implies, carboxylic acids are acidic, meaning that they are readily deprotonated to form the conjugate base form, called a carboxylate (much more about carboxylic acids in Chapter )9146 PEG average M n 5000, PDLLA average M n 000\ ch_3ch_2n(ch_3)ch_2ch_3 {/eq} IUPAC name During the naming of compound involving amine functional group, the parent chain will be the one which have more number of carbon atoms

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CH 3 CH 2 CH 2 NHCH 3;A carboxyl group (COOH) is a functional group consisting of a carbonyl group (C=O) with a hydroxyl group (OH) attached to the same carbon atom Carboxyl groups have the formula C(=O)OH, usually written as COOH or CO 2 H Carboxylic acids are a class of molecules which are characterized by the presence of one carboxyl groupSolution There is only one alkyl group attached to the nitrogen atom, so the amine is primary A group of three carbon atoms (a propyl group) is attached to the NH 2 group through an end carbon atom, so the name is propylamine There are two methyl groups and one ethyl group on the nitrogen atom

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 Match the name or structure with its functional group Each molecule has only one functional group My choices are alkane, alcohol, alkyne, carboxylic acid, alkene, aldehyde, ketone, ester, and ether 1 2propanol alcohol 2 social studies An interest group that focuses on policy benefits for senior citizens would be an example of a(n) aIn traditional names various qualifiers are used to label isomers, for example, isopropanol (IUPAC name propan2ol) is an isomer of npropanol (propan1ol) The term moiety has some overlap with the term "functional group"The functional group contained in the compound CH3CH2OCH2CH3 is a(n) ether The functional group contained in the compound CH3CH2CH=CHCH3 is a(n) alkene What is the name of the alkyl group CH3 CH2 CH2 ?

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Amides

CH 3 CH 2 Cl Chloroethane or ethyl chloride Nucleophilic subsitution;2 benzylamine NH 2 aniline N diisopropylethylamine Hunig's base Amides R'(C=O)NH 2 primary R'C(=O)NHR secondary R'(C=O)NR 2 tertiary CH 3 NH 2 O acetamide Ph NH 2 O benzamide H N(CH 3) 2 O N,Ndimethylformamide DMF N O Nmethylpyrrolidone N H piperidine N H pyrrolidine O N H morpholine Azo Ph N N Ph azobenzene Carbamates (urethanes) Et 2N OMe O methyl N,Ndiethylcarbamate Me 2N Cl O N,Ndimethylcarbamoyl chloride Ph N NThe names of alkenes and alkynes are based on the names of alkanes, but the suffix of the name varies to indicate the functional group present For example, a twocarbon compound containing a double bond, CH 2 =CH 2 , is called ethene rather than ethane

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CH 3 CH 2 CH 2 NHCH 3 Solution There is only one alkyl group attached to the nitrogen atom, so the amine is primary A group of three carbon atoms (a propyl group) is attached to the NH 2 group through an end carbon atom, so the name is propylamine There are two methyl groups and one ethyl group on the nitrogen atom(functional group) Generic formula Example Example name propanol Alkyl halide R X fluoride chloride bromide CH3CH2COCH3 methyl propanoate O CH3CH2CN(CH3)2 N,Ndimethylpropanamide Title functional_groupscdx AuthorFAMILY FUNCT GROUP EXAMPLE SUFFIX Hydrocarbons Alkane or (only single bonds) ethane –aneH Alkene C ethylene C H2CCH C HCCH C C C C C C CX H3CCl COH H3COH COC H3COCH3 CN H3CNH2 CCH O HCC O OH CCC O HCC O CH3 CCO O H HCCOCH3 CCOC O C H3CC O OCCH3 CCOC HCCOCH3 CCN O HCC O NH2 C C C C C C H H HH H Title Microsoft Word Functional Groups

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O C OH (with an oxygen double bonded above the Carbon) A carboxylic acid is named in the IUPAC system by replacing the e in the name of the parent alkane with ________ oic acid The functional group in acetic acid is called the ________ carboxyl group The IUPAC name of this compound is ________ A butanol line structure with a chlorineElimination Aryl halides C 6 H 5 Cl Chlorobenzene Electrophilic & nucleophilic aromatic substituion Alcohols CH 3 CH 2 OH Ethanol or ethyl alcohol Dehydration;Manufacturer Name Melting Point (°C) Physical Form Purity Agency Format Functional Group Industry Markush Class Markush Group Organoleptic Class Organoleptic Subclass Special Grade analytical standard (CH 3)COO m CH 2 CH 2 O n CH 3 Product Number Product Description SDS;

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 Example 9 Name and classify each compound 1 CH 3 CH 2 CH 2 NH 2 2 3 CH 3 CH 2 NHCH 2 CH 3 4 CH 3 CH 2 CH 2 NHCH 3 Solution There is only one alkyl group attached to the nitrogen atom, so the amine is primaryContaining functional group 4 2 Suffix basic name derived by adding ending of major functional group (FG) 3 2° amine N CH3 H3C H3C trimethylamine 3° amine N H H H ammonia N CH3 H3C H3C trimethylammonium ion 4° ammonium (salt) H If add four groups everything changes!If not, give the correct names 1Methyoxyethan2ol Medium View solution Fill in the blanks The functional group in an alcohol is _____ and its suffix in IUPAC system is _____ Medium View solution View more Learn with content Watch learning videos, swipe through stories, and browse through concepts Concepts > Videos >

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The smaller alkyl group forma a part of the Nalkyl group while the larger alkyl groupIt is a 3^ Amine as two methy group is directly attached to N Since there are 4 carbon in the longest chain so it is butane

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